Contrasting water–rock interaction behaviors of antimony and arsenic in contaminated rivers around an antimony mine,Hunan Province,China     

《Chemie der Erde / Geochemistry》2021,81(2):125748

Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.  相似文献   

Composition and origin of the volatile components released from the Pesyanoe aubrite by stepwise crushing and heating     

《Chemie der Erde / Geochemistry》2021,81(1):125686

Aubrites are achondritic meteorites (enstatite pyroxenites) that were formed in highly reduced magmatic environments on a differentiated parent body sharing a common oxygen isotope reservoir with enstatite chondrites (EC), Earth and Moon, and could be considered as a geochemical model of the early proto-Earth. Some pyroxenes of the Pesyanoe aubrite have high abundance of gaseous inclusions, captured during the crystallization of the rocks. Investigation of the inclusions by IR spectroscopy reveals presence of OH⁻ groups and C–H bonds. The former are assigned to protonated point defects in enstatite lattice and the latter to compounds occupying void walls. Molecular water and CO₂ were not observed. Volatile components released from the samples of the Pesyanoe enstatite by stepwise crushing and heating are composed of CO₂, H₂O and a non-condensable phase. Hydrogen isotopic composition of volatiles extracted in form of molecular water in Px-separates varies in the range δD = −61 – −84‰ with mean value of δD = −73 ± 16‰ VSMOW and is within the ranges of ECs and Earth’s mantle. The total abundance of H₂ in the pyroxene of Pesyanoe were estimated as at least 0.047 ppm that is too low in comparison with that of enstatite chondrites (≥30 ppm H₂) and could indicate nearly complete degassing of the Pesyanoe primitive precursor material during the Pesyanoe parent body accretion or a mantle degassing in igneous differentiation process. In a last case a primitive precursor could have D/H ratio different from that of enstatite chondrites.  相似文献   

燕辽海盆中元古界下马岭组沉积期的物源性质与古地理环境     

高志勇  王华建  冯佳睿  罗忠  张宇航  李晓红 《地质学报》2021,95(12):3606-3628

通过对河北省张家口下花园区夏家沟古城梁、怀来县赵家山等剖面地质测量,分析了1400 Ma前沉积的下马岭组岩性变化、沉积序列与海平面升降演化、岩石矿物组分与重矿物组合,认为下马岭组沉积时期发育温暖湿润的气候条件及多期热带风暴作用,早期的大规模风暴与浊流等事件沉积,晚期的浅海陆棚风暴岩、深水陆棚泥页岩、细粒浊积岩及安静水体的泥灰岩透镜体(灰泥饼)等是其鲜明的沉积响应.该时期发育一次长期缓慢的海平面上升-下降过程,对应一个二级层序.内幕可细分为五次海平面升降变化,对应五个三级层序;下马岭组沉积早期的物质组分主要以砂质、泥质为主,晚期转化为以泥质、灰质、云质为主,砂质减少,两种类型的物质组合系统先后影响燕辽裂陷槽;下马岭组沉积时期,具有双物源性质,除了主要来自于东部的山海关古隆起外,晚期可能也有西部山西古陆提供物源,来自北部的沉积物源不发育,推测北部的内蒙-冀北隆起(内蒙地轴)不存在,燕辽盆地具有西陡东缓的箕状断陷盆地特征,盆地古地形、物源供给变化与多级次海平面振荡变化控制了下马岭组沉积物的时空演化特征.该研究为1400 Ma前华北克拉通北部燕辽盆地岩相古地理的恢复提供了重要参考.  相似文献   

基于逻辑回归的四川青川县区域滑坡灾害预警模型          下载免费PDF全文

方然可  刘艳辉  苏永超  黄志全 《水文地质工程地质》2021,48(1):181-187

四川省青川县滑坡灾害群发,点多面广,区域滑坡灾害预警是有效防灾减灾的重要手段,预警模型是成功预警的核心。由于研究区滑坡诱发机理复杂、调查监测大数据及分析方法不足等原因,传统区域地质灾害预警模型存在预警精度有限、精细化不足等问题。文章在青川县地质灾害调查监测和降水监测成果集成整理与数据清洗基础上,构建了青川县区域滑坡灾害训练样本集,样本集包括地质环境、降雨等27个输入特征属性和1个输出特征属性,涵盖了青川县近9年（2010—2018年）全部样本,数量达1 826个（其中,正样本613个,负样本1 213个）。基于逻辑回归算法,对样本集进行5折交叉验证学习训练,采用贝叶斯优化算法进行模型优化,采用精确度、ROC曲线和AUC值等指标校验模型准确度和模型泛化能力。其中,ROC曲线也称为“受试者工作特征”曲线;AUC值表示ROC曲线下的面积。校验结果显示,基于逻辑回归算法的模型训练结果准确率和泛化能力均较好（准确率94.3%,AUC为0.980）。开展区域滑坡实际预警时,按训练样本特征属性格式,输入研究区各预警单元27个特征属性,调用预先学习训练好的模型,输出滑坡灾害发生概率,根据输出概率分段确定滑坡灾害预警等级。当输出概率P≥40%且P<60%时,发布黄色预警;当输出概率P≥60%且P<80%时,发布橙色预警;当输出概率P≥80%时,发布红色预警。  相似文献   

基于水热耦合的青藏高原分布式水文模型——Ⅱ.考虑冰川和冻土的尼洋河流域水循环过程模拟          下载免费PDF全文

刘扬李  周祖昊  刘佳嘉  王鹏翔  李玉庆  朱熠明  姜欣彤  王康  王富强 《水科学进展》2021,32(2):201-210

尼洋河流域是雅鲁藏布江第四大支流,受冰川、积雪和冻土影响,水循环关系极其复杂。为深入研究该区域内的水文循环过程,本文在寒区水循环模型（WEP-COR）的基础上,针对青藏高原气候和地质特点,构建了耦合“积雪-土壤-砂砾石层”连续体和“积雪-冰川”水热过程模拟的青藏高原分布式水循环模型（WEP-QTP）。在尼洋河流域通过对2013—2016年的流量过程模拟发现,工布江达和泥曲站的逐月流量Nash-Sutcliffe效率系数分别达到0.810和0.752,比改进前的0.430和0.095有明显提升;以2015年为例,对比WEP-COR和WEP-QTP模型发现,WEP-QTP模型在汛期特别是主汛前（冻土融化期）模拟的流量过程不会出现较大的波动,模拟得到的逐日流量Nash-Sutcliffe效率系数相比WEP-COR从-0.67提高到0.54。模型增强了地下水含水层的调节作用,使得流量过程更加平稳且接近实测,研究结果表明,WEP-QTP模型适用于青藏高原的水文模拟。  相似文献   

自然与人类活动叠加影响下晋祠泉域岩溶地下水动态特征     

王志恒  梁永平  申豪勇  赵春红  唐春雷  谢浩  赵一 《吉林大学学报(地球科学版)》2021,51(6):1823-1837

为了查明山西省晋祠泉泉水断流、泉口水位下降及近年来泉口水位回升的原因,为泉水复流工作提供理论参考,以长系列气象、水文、开采量、泉流量、地下水位等资料为基础,在详细分析了晋祠泉域不同水动力分区年内、年际动态特征的基础上,从自然气候与人类活动两方面出发,阐述了不同历史时期晋祠泉域岩溶水位变化的影响因素。结果表明：1956-1994年,因20世纪80、90年代人工开采量达到历史高峰期,一度超过2.4 m³/s,且80年代以后我国北方干旱化发展趋势较为严重,晋祠泉水流量逐渐减小直至断流;1994-2008年,人工开采量虽有一定程度减少,但仍维持在2.0 m³/s左右,且恰逢连续枯水年,降水量、河流径流量较多年平均值分别减小了11%和27%,此阶段泉口水位快速下降至历史最低值;2008年以后进入相对丰水期,在采取多项措施减少泉域岩溶水开采量的同时,汾河二库蓄水水位逐步抬高,其对岩溶水的渗漏补给量在经历了约2 a的滞后期后到达泉域排泄区,晋祠泉口水位近年来逐步回升。  相似文献   

山东省广饶县地下水位多年动态及其地质环境效应分析     

刘帅  刘志涛  段晓飞  冯颖  蒋书杰  黄松 《中国地质调查》2021,8(3):49-57

山东省广饶县地下淡水资源丰富,是本区工农业生产和生活用水的重要水源,长期大量开采地下水引发了地下水降落漏斗、咸水入侵、地面沉降等地质环境问题。通过对广饶县地下水多年监测资料的整理和分析,揭示了本区地下水水位的变化规律,预测了地下水水位的变化趋势。分析表明: 在现状开采条件下,浅层地下水降落漏斗已基本稳定,无加重趋势。考虑地面沉降和咸水入侵的发展趋势,提出深层地下水的约束埋深不应大于80 m,甄庙地区咸水入侵临界水位为10 m,这为当地地下水的合理开采与环境地质问题的防治提供了依据。  相似文献   

泰青威天然气管道临朐段水毁灾害分布特征与风险评价     

张成信  魏龙飞  唐尧  王艳超  代晓光  任永健 《中国地质调查》2021,8(5):108-114

对泰青威天然气管道临朐段地质灾害发育特征进行调查研究发现,临朐段地质灾害类型主要为水毁灾害,具体可分为坡面水毁、河沟道水毁和台田地水毁。野外地质灾害实地调查临朐段管道沿线共发现地质灾害15处,其中坡面水毁点6处,河沟道水毁点4处,台田地水毁点5处。采用定性与半定量相结合的评价方法对其进行地质灾害风险评价,结果表明: 地质灾害风险等级较高的有1处,占6.66%; 风险等级中等的有4处,占26.67%; 风险等级较低的有10处,占66.67%。根据管道沿线地形地貌、地质灾害发育密度、风险等级等因素,划分地质灾害中易发区61 km,低易发区10 km,管道沿线以地质灾害中易发区为主。最后,针对不同类型、不同风险等级地质灾害提出了相应的防治消减措施,为后期管道安全运营和风险整治决策提供了有效的技术依据。  相似文献   

Migration and speciation transformation mechanisms of mercury in undercurrent zones of the Tongguan gold mining area,Shaanxi Loess Plateau and impact on the environment     

《China Geology》2021,4(2):311-328

In order to study the migration and transformation mechanism of Hg content and occurrence form in subsurface flow zone of gold mining area in Loess Plateau and its influence on water environment, the field in-situ infiltration test and laboratory test were carried out in three typical sections of river-side loess, alluvial and proluvial strata in Tongguan gold mining area of Shaanxi Province, and the following results were obtained: (1) The source of Hg in subsurface flow zone is mainly caused by mineral processing activities; (2) the subsurface flow zone in the study area is in alkaline environment, and the residual state, iron and manganese oxidation state, strong organic state and humic acid state of mercury in loess are equally divided in dry and oxidizing environment; mercury in river alluvial or diluvial strata is mainly concentrated in silt, tailings and clayey silt soil layer, and mercury has certain stability, and the form of mercury in loess is easier to transform than the other two media; (3) under the flooding condition, most of mercury is trapped in the silt layer in the undercurrent zone where the sand and silt layers alternate with each other and the river water and groundwater are disjointed, and the migration capacity of mercury is far less than that of loess layer and alluvial layer with close hydraulic connection; (4) infiltration at the flood level accelerates the migration of pollutants to the ground; (5) the soil in the undercurrent zone is overloaded and has seriously exceeded the standard. Although the groundwater monitoring results are safe this time, relevant enterprises or departments should continue to pay attention to improving the gold extraction process, especially vigorously rectify the small workshops for illegal gold extraction and the substandard discharge of the three wastes, and intensify efforts to solve the geological environmental problems of mines left over from history. At present, the occurrence form of mercury in the undercurrent zone is relatively stable, but the water and soil layers have been polluted. The risk of disjointed groundwater pollution can not be ignored while giving priority to the treatment of loess and river alluvial landform areas with close hydraulic links. The research results will provide a scientific basis for water conservancy departments to groundwater prevention and control in water-deficient areas of the Loess Plateau.  相似文献   

The relationship between groundwater and natural vegetation in Qaidam Basin          下载免费PDF全文

Dang Xue-ya  Lu Na  Gu Xiao-fan  Jin Xiao-mei 《地下水科学与工程》2021,9(4):341-349

To accurately evaluate ecological risks trigged by groundwater exploitation, it must be clarified the relationship between vegetation and groundwater. Based on remote sensing data sets MOD13Q1, groundwater table depth (WTD) and total dissolved solids (TDS), the relationship between groundwater and natural vegetation was analyzed statistically in the main plain areas of Qaidam Basin. The results indicate that natural vegetation is groundwater-dependent in areas where WTD is less than 5.5 m and TDS is less than 7.5 g/L. Aquatic vegetation, hygrophytic vegetation and hygrophytic saline-alkali tolerant vegetation are mainly distributed in areas with WTD <1.1 m. Salt-tolerant and mesophytic vegetation mainly occur in areas with WTD of 1.4-3.5 m, while the xerophytic vegetation isprimarily present in areas where WTD ranges from 1.4 m to 5.5 m. Natural vegetation does not necessarily depend on groundwater in areas with WTD >5.5 m. For natural vegetation, the most suitable water TDS is less than 1.5 g/L, the moderately suitable TDS is 1.5-5.0 g/L, the basically suitable TDS is 5.0-7.5 g/L, and the unsuitable TDS is more than 7.5 g/L.  相似文献